Multidimensional Solid-State NMR and Polymers

Multidimensional Solid-State NMR and Polymers

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NMR spectroscopy is the most valuable and versatile analytical tool in chemistry. While excellent monographs exist on high-resolution NMR in liquids and solids, this is the first book to address multidimensional solid-state NMR. Multidimensional techniques enable researchers to obtain detailed information about the structure, dynamics, orientation, and phase separation of solids, which provides the basis of a better understanding of materials properties on the molecular level.Dramatic progress-much of it pioneered by the authors-has been achieved in this area, especially in synthetic polymers. Solid-state NMR now favorably competes with well-established techniques, such as light, x-ray, or neutron scattering, electron microscopy, and dielectric and mechanical relaxation. The application of multidimensional solid-state NMR inevitably involves use of concepts from different fields of science. This book also provides the first comprehensive treatment of both the new experimental techniques and the theoretical concepts needed in more complex data analysis. The text addresses spectroscopists and polymer scientists by treating the subject on different levels; descriptive, technical, and mathematical approaches are used when appropriate. It presents an overview of new developments with numerous experimental examples and illustrations, which will appeal to readers interested in both the information content as well as the potential of solid-state NMR. The book also contains many previously unpublished details that will be appreciated by those who want to perform the experiments. The techniques described are applicable not only to the study of synthetic polymers but to numerous problems in solid-state physics, chemistry, materials science, and biophysics. Key Features * Presents original theories and new perspectives on scattering techniques * Provides a systematic treatment of the whole subject * Gives readers access to previously unpublished material * Includes extensive illustrationsThus, we obtain the formal solution: M(t) = 1. ... The density-operator description of spin Systems, which combines quantum mechanics and statistical mechanics, will be discussed, and it will be ... and other few-level systems, it is, however, more convenient to describe the system in terms of the density operator 6 (t) ( Sakurai, anbsp;...

Title:Multidimensional Solid-State NMR and Polymers
Author:Klaus Schmidt-Rohr, Hans Wolfgang Spiess
Publisher:Elsevier - 2012-12-02


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