This chemistry is also successfully extended to vinylogous esters and thioesters. The products are versatile synthons for organic synthesis, serving as masked 1, 3-dicarbonyl compounds in which the two ketone groups and adjacent carbons may be selectively functionalized.GC analyses were performed on a HP 6850 series GC system using a Agilent Technologies HP-1 GC column (30 m length, 0.32 mm I.D., 0.25 um film). Chiral HPLC analyses were performed on a Themo Separation Products Spectra Series anbsp;...
|Title||:||Palladium Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Unstabilized Enolates: Scope, Mechanism and Synthetic Applications|
|Publisher||:||ProQuest - 2009|